Here, an unprecedented phenomenon in which 7‐coordinate lanthanide metallomesogens, which align via hydrogen bonds mediated by coordinated H2O molecules, form micellar cubic mesophases at room temperature, creating body‐center...
Ryosuke Ando Ryo Watanuki Kazuhiro Kudo Hyuma Masu Masatoshi Sakai
Solids 4(3) 201-212 Aug 2023
The metal–insulator transition induced by the gate electric field in the charge order phase of the α-(BEDT-TTF)2I3 single-crystal field-effect transistor (FET) structure was clearly observed near the phase transition temperature. An abrupt increas...
Takahiro Ohkubo Nao Komiyama Hyuma Masu Keiki Kishikawa Michinari Kohri
Inorganic chemistry 62(30) 11897-11909 Jul 2023
The seven-coordinate Ho(III) aqua-tris(dibenzoylmethane)(DBM) complex, referred to as Ho-(DBM)3·H2O, was first reported in the late 1960s. It has a threefold symmetric structure, with Ho at the center of three dibenzoylmethane ligands and hydrogen...
Azumi Akiyama Hyuma Masu Michinari Kohri Keiki Kishikawa
Materials Letters 343 Jul 2023
Tetraalkoxylated diphenylureas U-3,4-Scit and U-3,4-raccit were synthesized from chiral and racemic citronellyl bromides as starting materials, respectively. To prepare pyroelectric crystals, these two compounds were slowly cooled from their molte...
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