小倉 裕直

Facing the goal of carbon neutrality, energy supply chains should be more low-carbon and flexible. A solar chemical heat pump (SCHP) is a potential system for achieving this goal. Our previous studies developed a silicone-oil-based phase-change material (PCM) mixture as a PCM fluid for enhancing heat recovery above 373 K in the solar collector (SC) of the SCHP. The PCM fluid was previously tested to confirm its dispersity and flow properties. The present study proposed a 3D computational fluid dynamics model to simulate the closed circulation loop between the SC and reactor using the PCM fluid. The recovered heat in the SC was studied using several flow rates, as well as the PCM weight fraction of the PCM fluid. Furthermore, the net transportable energy is considered to evaluate the ratio of recovered heat and relative circulation power. As a result, it was verified that the recovered heat of the SC in the experiment and simulation is consistent. The total recovered heat is improved using the PCM fluid. A lower flow rate can enhance the PCM melting mass and the recovered heat although sensible heat amount increases with the flow rate. The best flow rate was 1 L/min when the SC area is 1 m2. Furthermore, the higher PCM content has higher latent heat. On the other hand, the lower content PCM can increase the temperature difference between the SC inlet and outlet because of the lower PCM heat capacity. For the 1 L/min flow rate, 2 wt% PCM fluid has shorter heat-storing time and larger net transportable energy than 0 wt% PCM fluid (426 kJ←403 kJ) for the SCHP unit.

Few studies have investigated personal exposure concentrations of not only some volatile organic compounds but also more types of chemicals including acidic gases and acrolein. We measured the personal exposure concentrations of 35 chemicals including these chemicals in indoor and outdoor air in Chiba-shi, Japan, for 7 days in summer and winter to assess the associated health risks in 22 people. The personal exposure concentrations of nitrogen dioxide were higher in winter than in summer, and those of formaldehyde, p-dichlorobenzene, and tetradecane were higher in summer than in winter. The personal exposure concentrations were mostly equal to or lower than the concentrations in indoor air, contrary to the results of a lot of previous studies. The high-risk chemicals based on personal exposure concentrations were identified as acrolein (max. 0.43 μg/m3), benzene (max. 3.1 μg/m3), and hexane (max. 220 μg/m3) in summer, and acrolein (max. 0.31 μg/m3), nitrogen dioxide (max. 320 μg/m3), benzene (max. 5.2 μg/m3), formic acid (max. 70 μg/m3), and hexane (max. 290 μg/m3) in winter. In addition, we estimated personal exposure concentrations according to the time spent at home and the chemical concentrations in indoor and outdoor air. We found that the estimated concentrations of some participants largely differed from the measured ones indicating that it is difficult to estimate personal exposure concentrations based on only these data.