We report the synthesis of seven‐membered carbocycles through the dearomative intermolecular reaction of benzofurans with vinylcyclopropanes. The significant feature of this method involves activating benzofurans through energy transfer from an ac...
European Journal of Organic Chemistry 2023年8月 [査読有り]
A trichloromethylative olefin lactonization reaction using an iridium photoredox catalyst was developed. The reactions proceeded at room temperature for olefins with various substituents and substitution patterns, and a variety of lactones with a ...
Utility of N-acylpyrroles as activated monodentate ester surrogates is demonstrated in several catalytic asymmetric reactions. In the direct Mannich-type reaction, the N-acylpyrrole was used as a donor, and an In(O-i-Pr)<sub>3</sub>/li...