Bioorganic and Medicinal Chemistry 26(4) 824-832 2018年2月 [査読有り]
Mycoplasma pneumoniae expresses β-glycolipids (β-GGLs) in cytoplasmic membranes, which possess a unique β(1 → 6)-linked disaccharide epitope, which has high potential in biochemical and medicinal applications. In the present study, a series of β-G...
Journal of Carbohydrate Chemistry 36(8-9) 307-324 2017年11月 [査読有り]
A facile methodology is proposed for regioselective conjugation between glycosyl donors and acceptors towards the development of regioselective 1,2-cis-glycosylation method. ortho-Formylphenyl 1-thio-β-d-galactopyranoside was regioselectively teth...
Cell-membrane glycerophospholipids and glycolipids have a common asymmetric skeleton of 1,2-diacyl-sn-glycerols. The 1,2-diacyl moiety in solutions permits a rapid equilibrium among three helical conformers, namely gt(+), gg(-), and tg, to display...
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 13 1999-2009 2017年9月 [査読有り]
Cell-membrane glycerolipids exhibit a common structural backbone of asymmetric 1,2-diacyl-sn-glycerol bearing polar head groups in the sn-3 position. In this study, the possible effects of sn-3 head groups on the helical conformational property ar...
TRENDS IN GLYCOSCIENCE AND GLYCOTECHNOLOGY 26(151) 119-130 2014年9月 [査読有り][招待有り]
Thioglycosides are widely used in the synthesis of oligosaccharides because they provide high levels of chemical stability and can be chemoselectively activated in a glycosylation reaction. Thioglycosides, however, are prepared from thiols, which ...