Here, an unprecedented phenomenon in which 7‐coordinate lanthanide metallomesogens, which align via hydrogen bonds mediated by coordinated H2O molecules, form micellar cubic mesophases at room temperature, creating body‐center...
Yuta Fujita Kotona Kohaku Nao Komiyama Kazuya Ujiie Hyuma Masu Takashi Kojima Hiroki Wadati Hirofumi Kanoh Keiki Kishikawa Michinari Kohri
ChemNanoMat 8(7) Apr 2022
Holmium (Ho) is a lanthanide element with a high magnetic moment. Here, we create an amorphous metal-organic framework (MOF) that has no long-range periodic order but retains the basic components of MOF by using isophthalic acid as an organic link...
Mikiya Yamamoto Koki Ando Mizuki Inoue Hirofumi Kanoh Mai Yamagami Takeshi Wakiya Eiji Iida Tatsuo Taniguchi Keiki Kishikawa Michinari Kohri
ACS APPLIED POLYMER MATERIALS 2(6) 2170-2178 Jun 2020
The present report describes the preparation of lanthanide-doped colorless magnetic materials based on poly-beta-ketoester particles. Monodisperse poly(2-acetoacetoxy ethyl methacrylate) (PAAEM) particles were prepared by dispersion polymerization...
ACS APPLIED POLYMER MATERIALS 2(5) 1800-1806 May 2020
Here, we have demonstrated the production of colorless and full-color magnetic nanoparticles based on holmium (Ho)-doped polymers, which could not be achieved with conventional dark brown iron oxide magnetic nanoparticles. The coordination of Ho, ...
[Cu(4,4 '-bipyridine)(2)(BF4)(2)] (ELM-11), an elastic layer-structured MOF (metal-organic framework), is expected to be a sophisticated CO2 reservoir candidate because of its high capacity and recovery efficiency for CO2 sorption. While ELM-11 sh...
Materials that can undergo structural or phase transformations have attracted considerable attention as functional materials in many fields for electric, magnetic, optical, adsorption, separation, or catalysis applications. Outstanding examples of...
Iodine Chemistry and Applications 9781118466292 15-23 Nov 2014
Iodine is one of the essential elements for human nutrition. Iodine measurement in biological samples is carried out almost exclusively by one of two methods: One is a kinetic spectrophotometric method called the Sandell-Kolthoff reaction based on...
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