Here, an unprecedented phenomenon in which 7‐coordinate lanthanide metallomesogens, which align via hydrogen bonds mediated by coordinated H2O molecules, form micellar cubic mesophases at room temperature, creating body‐center...
Yuta Fujita   Kotona Kohaku   Nao Komiyama   Kazuya Ujiie   Hyuma Masu   Takashi Kojima   Hiroki Wadati   Hirofumi Kanoh   Keiki Kishikawa   Michinari Kohri   
ChemNanoMat 8(7) 2022年4月
Holmium (Ho) is a lanthanide element with a high magnetic moment. Here, we create an amorphous metal-organic framework (MOF) that has no long-range periodic order but retains the basic components of MOF by using isophthalic acid as an organic link...
The present report describes the preparation of lanthanide-doped colorless magnetic materials based on poly-beta-ketoester particles. Monodisperse poly(2-acetoacetoxy ethyl methacrylate) (PAAEM) particles were prepared by dispersion polymerization...
Here, we have demonstrated the production of colorless and full-color magnetic nanoparticles based on holmium (Ho)-doped polymers, which could not be achieved with conventional dark brown iron oxide magnetic nanoparticles. The coordination of Ho, ...
[Cu(4,4 '-bipyridine)(2)(BF4)(2)] (ELM-11), an elastic layer-structured MOF (metal-organic framework), is expected to be a sophisticated CO2 reservoir candidate because of its high capacity and recovery efficiency for CO2 sorption. While ELM-11 sh...
Water vapor adsorption on porous carbons has been actively studied because of its importance in various applications and basic science. However, the unique behavior and structure of water in carbon nanospaces have still been remained unclear. Carb...
Confinement of KI nanocrystals in nanoscale pores of single wall carbon nanohorn (SWCNH) and activated carbon fiber (ACF) below 0.1 MPa induces the formation of high pressure phase solid, although compression under 1.9 GP is necessary for formatio...
JOURNAL OF PHYSICAL CHEMISTRY C 116(41) 21870-21873 2012年10月
High-density CH4 storage using adsorption techniques is an important issue in the use of CH4 as a clean energy source. The CH4 adsorption mechanism has to be understood to enable innovative improvements in CH4 adsorption storage. Here, we describe...