Here, an unprecedented phenomenon in which 7‐coordinate lanthanide metallomesogens, which align via hydrogen bonds mediated by coordinated H2O molecules, form micellar cubic mesophases at room temperature, creating body‐center...
Films that exhibit different metallic luster on the front and back, called Janus metallic films, have broad applications ranging from design materials to optical devices. However, the fabrication of these films is often a complicated process invol...
The seven-coordinate Ho(III) aqua-tris(dibenzoylmethane)(DBM) complex, referred to as Ho-(DBM)3·H2O, was first reported in the late 1960s. It has a threefold symmetric structure, with Ho at the center of three dibenzoylmethane ligands and hydrogen...
Azumi Akiyama   Hyuma Masu   Michinari Kohri   Keiki Kishikawa   
Materials Letters 343 2023年7月
Tetraalkoxylated diphenylureas U-3,4-Scit and U-3,4-raccit were synthesized from chiral and racemic citronellyl bromides as starting materials, respectively. To prepare pyroelectric crystals, these two compounds were slowly cooled from their molte...